By Holly George-Warren, Us Magazine, Mark Seliger, Chris Mundy
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238 Thus, H r (CCl 4 ) H r (C 8 H18 ) 117 . It takes more energy to evaporate HCN from CCl4 than from octane. 13. At 170qC and 25 bar: z H2 is above 1 H2 zamine is well below 1 1 z HCl is slightly below 1 z HCl 0 a) 1 yamine A mixture of amine and H2 is expected to exhibit positive deviations from Amagat’s law. b) Since amine and HCl can complex, mixtures will exhibit negative deviations from Amagat’s law. c) z argon 1 z z HCl 0 yargon 1 Solutions Manual 38 The strong dipole-dipole attractive forces between HCl molecules cause z HCl 1 , while argon is nearly ideal.
This constant may be measured by relating it to characteristic frequency X through: X 1 2S b K mC mO mC m O g where mC and mO are, respectively, the masses of carbon and oxygen atoms. Infrared spectrum will show strong absorption at X. Argon has only translational degrees of freedom while CO has, in addition, rotational and vibrational degrees of freedom. Therefore, the specific heat of CO is larger than that of argon. 7. Electron affinity is the energy released when an electron is added to a neutral atom (or molecule).
15. a) They are listed in Page 106 of the textbook: 1. 2. 3. 4. Q can be factored so that Qint is independent of density. Classical (rather than quantum) statistical mechanics is applicable. *total ¦ (*Pairs ) (pairwise additivity). * / H F (r / V ) (universal functionality). b) In general, assumption 4 is violated. But if we fix the core size to be a fixed fraction of the collision diameter, then Kihara potential is a 2-parameter (V, H) potential that satisfies corresponding states. c) Hydrogen (at least at low temperatures) has a de Broglie wavelength large enough so that quantum effects must be considered and therefore assumption 2 is violated.
Brad Pitt (Editors of Us Magazine) by Holly George-Warren, Us Magazine, Mark Seliger, Chris Mundy