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In this Section therefore most of the necessary theory for the treatment of d x configurations in pseudo-axial (Cv) symmetry has been developed. For the interpretation of the d - d electronic spectra of sandwich complexes of the 3 d elements the strong field treatment excluding spin-orbit coupling usually suffices, and where spin-orbit effects are clearly involved, for example in determining the relative intensities of spin-forbidden bands, the standard perturbation methods are normally adequate.

110 6. Charge-Transfer Spectra and Molecular Orbital Calculations . . . . . . . . . . 126 7. Photoelectron Spectra 137 ........................................ 8. Conclusions . . . . . . . . . . . . . . . . . . . . . . . 154 9. References . . . . . . . . . . . . . . . . . . . . . . . . 156 Abbreviations used: Cp = CsH s, MeCp = CH3CsH4, Bz = C6H6, Tol = CH3C6Hs, Mes = 1,3,5-(CH3)3C6H3, HMBz = (CH3)6C6, Ch = C7H7, Cot = C8H 8.

90, 1499 (1968). , Mallory, F. : J. Amer. Chem. Soe. 92, 1460 (1970). Dobson, R. : J. Amer. Chem. Soc. 93, 6188 (1971). , Odell, B. : J. Amer. Chem. Soe. 92, 7091 (1970). : J. Amer. Chem. Soc. 96, 7892 (1974). : Helv. Chim. Aeta 55, 893 (1972). : J. Amer. Chem. Soe. 94, 779 (1972). Stohrer, W. " J. Amer. Chem. Soc. 94, 1661 (1972). , Wan, C. , Neagu, K: Molee. Phys. 19, 113 (1970). , Simonetta, M. : J. Chem. Soc. Perldn II 502, 1974. : Ace. Chem. Res. , Holder, R. : J. Amer. Chem. Soe. 95, 27. 28.

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