Aldol Reactions by Rainer Mahrwald PDF

By Rainer Mahrwald

ISBN-10: 1402087004

ISBN-13: 9781402087004

ISBN-10: 1402087012

ISBN-13: 9781402087011

Aldol Reactions offers a entire updated assessment of aldol reactions including:

  • Application of alternative steel enolates
  • Catalytic aldol additions catalyzed through diversified Lewis acids and Lewis bases
  • Enantioselective direct aldol additions
  • Antibodies and enzyme catalyzed aldol additions
  • The contemporary competitive improvement of organocatalyzed aldol additions.

The energy of every procedure is validated by means of a number of purposes in overall synthesis of usual items. the professionals and cons of those methodologies in regards to stereoselectivity, regioselectivity and alertness in overall synthesis of average items are mentioned. nice value is determined to the varied probabilities of the guide of aldol response to put in required configurations in advanced ordinary product synthesis.

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Conventional chiral enolates have been used for this purpose extensively. Several chiral auxiliaries have been developed to achieve this aim. 4. 3 Stereoselective formation of (Z)- or (E)-boron enolates of ketones or carboxylic esters and subsequent aldol addition Reactions of boron enolates of chiral oxazolidinones with aldehydes represent one of the most popular applications of asymmetric boron enolate aldol reactions. 34,35 As a consequence of (Z)-geometry of boron enolates employed in these reactions the formation of syn-configured products is observed.

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Solladie G (1996) In: Houben-Weyl, Methoden der Organischen Chemie, Helmchen G, Hoffmann RW, Mulzer J, Schaumann E (eds). Thieme, Stuttgart, vol E21b, p 1808 4. Bauder C (2008) Tetrahedron Lett 49:2243 5. He X, Morris JJ, Noll BC, Brown SN, Henderson KW (2006) J Am Chem Soc 128:13599 6. He X, Allan JF, Noll BC; Kennedy AR, Henderson KW (2005) J Am Chem Soc 127:6920 7. Allan JF, Henderson KW, Kennedy AR (1999) Chem Commun 1325 8. vanDraanen NA, Arseniyadis S, Crimmins MT, Heathcock CH (1991) J Org Chem 56:2499 9.

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